Journal of the Chemical Society, Dalton Transactions p. 2253 - 2264 (1991)
Update date:2022-08-29
Topics:
Uson, Rafael
Fornies, Juan
Tomas, Milagros
Ara, Irene
Casas, Jose M.
Martin, Antonio
Heterobinulear complexes of general formula a strong Pt->Ag bond <2.650(2), 14; 2.641(1), 24; and 2.692(2) Angstroem, 25> unsupported by covalent bridges, and short contacts between the o-F or o-Cl atoms of the C6X5 (X = F or Cl) groups and the Ag atom are present.The relative strength of such contacts is discussed.Methods for the synthesis of mixed pentachloro-pentafluorophenyl starting complexes 1-13 have been investigated.
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