Oxidation of 2-Methylcyclohexanone and Cyclohexanone by Dioxygen Catalyzed by Vanadium-Containing Heteropolyanions

DOI: 10.1021/jo00073a026

Source and publish data:

Journal of Organic Chemistry p. 5663 - 5665 (1993)

Update date:2022-08-17

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Authors:

Atlamsani, Ahmed

Bregeault, Jean-Marie

Ziyad, Mahfoud

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Article abstract of DOI:10.1021/jo00073a026

2-Methylcyclohexanone is oxidized by dioxygen in the presence of H(3+n)*aq to give 6-oxoheptanoic acid.Solvent effects are studied.The same precursors with cyclohexanone in aqueous acetic acid give adipic acid as the major product and other dicarboxylic acids by oxidation of 6-oxohexanoic acid.

Full text of DOI:10.1021/jo00073a026

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