Journal of the Chemical Society. Chemical communications p. 1371 - 1373 (1987)
Update date:2022-08-11
Topics:
Botting, Nigel P.
Akhtar, Mahmoud
Cohen, Mark A.
Gani, David
Kinetic experiments with 3-methylaspartase, using aspartic, 3-methylaspartic, and 3-ethylaspartic acid and the appropriate C-3 deuteriated isotopomers as substrates, reveal that C(3)-H bond cleavage is partially rate-limiting for 3-methylaspartic acid, much less rate-limiting for 3-ethylaspartic acid, and not rate-limiting at all for aspartic acid.
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