Tetrahedron Letters p. 747 - 750 (1991)
Update date:2022-08-17
Topics:
Nocher, Anne Marie Le
Metzner, Patrick
Reaction of enethiolizable thioketones 2 with one equivalent of meta-chloroperoxybenzoic acid affords quantitatively the corresponding E sulfines 1.In contrast to literature expectations, direct synthesis of aliphatic sulfines by oxidation of thiocarbonyl compounds is thus possible; no divinyl disulfide 4 has been formed.
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