Angewandte Chemie - International Edition p. 7636 - 7640 (2011)
Update date:2022-08-16
Topics:
Gutmann, Bernhard
Schwan, Alexander M.
Reichart, Benedikt
Gspan, Christian
Hofer, Ferdinand
Kappe, C. Oliver
It's field density, not temperature! Modifying the electric field strength in a microwave experiment can completely change the outcome of a reaction. Whereas a low field strength in Grignard reagent formation from Mg metal and aryl halide leads to acceleration of the initiation step, using a high field strength at the same temperature suppresses Mg insertion, favoring solvent decomposition and passivation of the Mg metal (see scheme). Copyright
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