Chemische Berichte p. 1709 - 1714 (1997)
Update date:2022-08-11
Topics:
Gross, Thoralf
Kempe, Rhett
Oehme, Hartmut
Tris(trimethylsilyl)silyllithium (1) reacts with methyl formate in diethyl ether (molar ratio 2:1) to give l,2-di(hypersilyl)ethylene 13. The formation of 13 proceeds through the intermediates formyl tris(trimethylsilyl)silane (4) and lithium bis[tris(trimethylsilyl)silyl]methoxide (5). In diethyl ether, the alkoxide 5 spontaneously eliminates lithium trimethylsilanolate thereby generating l,l-bis(trimethylsilyl)-2-[tris{trimethylsilyl)silyl]silene (9), which undergoes a formal [2+2] cycloaddition with the carbonyl compound 4 to afford 13. This was verified by crossover experiments. In pentane, the alkoxide 5 is moderately stable. Thus, the intermediate 5, prepared by reaction of 1 with tert-butyl formate in pentane, was protonated with water to give the di(hypersilyl)methanol 6 in good yield. The structure of 6 was elucidated by an X-ray crystal structure analysis, which expectedly revealed tremendous distortions of the molecular skeleton. Thus, the spatial demand of the two extended hemispherical (Me3Si)3Si groups forces a widening of the Si-C-Si angle at the central sp3 carbon atom to a value of 135.5°. WILEY-VCH Verlag GmbH, 1997.
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