
Russian Journal of General Chemistry p. 2120 - 2124 (2014)
Update date:2022-08-11
Topics:
Nalet'Ko
Pervova
Gorbunova
Zapevalov, A. Ya
Toporova
Saloutin
Reaction of (alkoxymethyl)oxiranes with thiourea in methanol has afforded the corresponding thiiranes, and catalyst-free thermal desulfurization of the products has been studied. The major products of desulfurization are alcohols and alkenes, both in the cases of (polyfluoroalkyloxymethyl)thiiranes and their non-fluorinated analogs. Longer alkyl chain in thiiranes favors formation of alcohols over alkenes formation in the course of desulfurization.
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