Deoxygenation of alcohols by the reactions of their xanthate esters with triethylsilane: An alternative to tributyltin hydride in the Barton-McCombie reaction

DOI: 10.1016/S0040-4039(00)97814-6

Source and publish data:

Tetrahedron Letters p. 5093 - 5096 (1990)

Update date:2022-08-11

Topics:

Authors:

Nicholas Kirwan

Roberts, Brian P.

Willis, Colin R.

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Article abstract of DOI:10.1016/S0040-4039(00)97814-6

O-Alkyl S-methyl dithiocarbonates derived from primary or secondary alcohols (ROH) react with trialkylsilanes in non-aromatic solvents to give the corresponding hydrocarbons RH in good yields; the reductions are promoted by thiols which act as polarity reversal catalysts.

Full text of DOI:10.1016/S0040-4039(00)97814-6

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