Tetrahedron Letters p. 5093 - 5096 (1990)
Update date:2022-08-11
Topics:
Nicholas Kirwan
Roberts, Brian P.
Willis, Colin R.
O-Alkyl S-methyl dithiocarbonates derived from primary or secondary alcohols (ROH) react with trialkylsilanes in non-aromatic solvents to give the corresponding hydrocarbons RH in good yields; the reductions are promoted by thiols which act as polarity reversal catalysts.
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