Deoxygenation of alcohols by the reactions of their xanthate esters with triethylsilane: An alternative to tributyltin hydride in the Barton-McCombie reaction

DOI: 10.1016/S0040-4039(00)97814-6

Source and publish data:

Tetrahedron Letters p. 5093 - 5096 (1990)

Update date:2022-08-11

Topics:

Authors:

Nicholas Kirwan

Roberts, Brian P.

Willis, Colin R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97814-6

O-Alkyl S-methyl dithiocarbonates derived from primary or secondary alcohols (ROH) react with trialkylsilanes in non-aromatic solvents to give the corresponding hydrocarbons RH in good yields; the reductions are promoted by thiols which act as polarity reversal catalysts.

Full text of DOI:10.1016/S0040-4039(00)97814-6

Products guided by the article

Product name:n-Octane

Cas No:111-65-9

R&D Labs maybe for 111-65-9

CHEM PLUS

Contact:0027-717-456976

Address:2ND FLOOR, 325 VAUSE ROAD, OVERPORT, 4001, SOUTH AFRICA
CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County
Guangzhou PI & PI Biotech Inc. Ltd.

Contact:+86-20-81716320

Address:13th Floor, Xinbao Technology Industrial Park, No. 2 Ruixiang Road, Huangpu District, Guangzhou,Guangdong,China
JIANGXI XINXIN CHEMICAL CO., LTD.

Contact:86-15957176628

Address:INDUSTRY ROAD 1, INDUSTRIAL PARK, HEKOU TOWN,YANSHAN COUNTY, JIANGXI PROVINCE, CHINA
Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,

Relevant to this article

ALTERNATIVE, SIMPLE ROUTE TO HYDROXYMETHYL CROWN ETHERS

Doi:10.1016/S0040-4039(00)93687-6
(1980)
Enantioselective organocatalytic direct aldol reactions of α-oxyaldehydes: Step one in a two-step synthesis of carbohydrates

Doi:10.1002/anie.200453716
(2004)
The first samarium(II)-mediated aryl radical cyclisation onto an aromatic ring

Doi:10.1039/b410457a
(2004)
Novel highly efficient fluoroionophores with a peri-effect and strong electron-donating receptors: TICT-promoted PET and signaling response to transition metal cations with low background emission

Doi:10.1016/S0040-4039(03)00186-2
(2003)
Effects of thiol modifiers on the kinetics of furfural hydrogenation over Pd catalysts

Doi:10.1021/cs500598y
(2014)
Facile Fabrication of Nickel/Heazlewoodite@Carbon Nanosheets and their Superior Catalytic Performance of 4-Nitrophenol Reduction

Doi:10.1002/cctc.201800889
(2018)

Article Doi