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Tris(2-pyridyl)phosphine Complexes of Ruthenium(II) and Rhodium(I). Hydroformylation of Hex-1-ene by Rhodium Complexes

DOI: 10.1039/DT9800000055

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 55 - 58 (1980)

Update date:2022-08-11

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Authors:

Kurtev, KurtiKurtev, Kurti

Ribola, DominiqueRibola, Dominique

Jones, Richard A.Jones, Richard A.

Cole-Hamilton, David J.Cole-Hamilton, David J.

Wilkinson, GeoffreyWilkinson, Geoffrey

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Article abstract of DOI:10.1039/DT9800000055

Complexes of ruthenium(II) and rhodium(I) containing tris(2-pyridyl)phosphine are described, examples being RuHCl3 and RhCl2.In certain cases, as in these, the nitrogen atom of one of the 2-pyridyl groups can act as a donor to give a P,N chelate ligand.In the presence of an excess of P(py)3 and at low CO + H2 (1 : 1) pressures, the complex RhH(CO)(PPh3)2 acts as a catalyst for the selective hydroformylation of hex-1-ene to n-heptanal.

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