Reductive transformation of α β-epoxy ketones and other compounds promoted through photoinduced electron transfer processes with 1,3-dimethyl- 2-phenylbenzimidazoline (DMPBI)

DOI: 10.1016/S0040-4020(99)00804-2

Source and publish data:

Tetrahedron p. 12957 - 12968 (1999)

Update date:2022-08-11

Topics:

Authors:

Hasegawa, Eietsu

Yoneoka, Akira

Suzuki, Kumiko

Kato, Teru

Kitazume, Takashi

Yanagi, Kazuhiro

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Article abstract of DOI:10.1016/S0040-4020(99)00804-2

Photoreactions of epoxy ketones, aromatic ketones, haloketones, and aromatic halides with 1,3-dimethyl-2-phenylbenzimidazoline (DMPBI) were studied. Photoinduced single-electron transfer from DMPBI to such substrates initiates the reactions, followed by radical rearrangement and reduction to finally give several reduced products in modest to good yields.

Full text of DOI:10.1016/S0040-4020(99)00804-2

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