Kinetics and Mechanism of Hydrolysis of Some Amine-Cyanoboranes in Acid Perchlorate Media

DOI: 10.1039/DT9910002929

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2929 - 2932 (1991)

Update date:2022-08-11

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Authors:

Das, Mrinal Kanti

Bandyopadhyay, Soumendra Nath

Bhattacharyya, Siddhartha

Banerjee, Rupendranath

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Article abstract of DOI:10.1039/DT9910002929

In acid media (+> = 0.02-0.2 mol dm^-3), isopropylamine- and diisopropylamine-cyanoborane are hydrolysed completely to boric acid, hydrogen, hydrogen cyanide and the salt of the corresponding amine.The reaction occurs in steps, viz.

Full text of DOI:10.1039/DT9910002929

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