Chemical Communications p. 13247 - 13249 (2014)
Update date:2022-08-11
Topics:
Rubinstein, Amir
Carmeli, Raanan
Neumann, Ronny
The H5PV2Mo10O40 polyoxometalate catalysed the electron transfer oxidation of sulphite to yield a sulphite radical, SO3- that upon addition of O2 yielded a peroxosulphate species efficient for the H5PV2Mo10O40 catalysed epoxidation of alkenes. The acidic polyoxometalate further catalysed hydrolysis of the epoxide to give vicinal diols in high yields. This journal is
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