Journal of Organic Chemistry p. 2910 - 2914 (1983)
Update date:2022-08-16
Topics:
Chow, Yuan L.
Marciniak, Bronislaw
Photolysis of butyrophenone, valerophenone, γ-methylvalerophenone, and acetophenone in methanol in the presence of triphenylphosphine gave triphenylphosphine oxide and 1-phenyl-1-methoxyalkanes in addition to the expected Norrish type II products.Kinetic studies of these photoreactions by steady-state measurements show that triplet-state ketones are quenched by Ph3P but that the corresponding biradicals do not interact with Ph3P.
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