Chemistry Letters p. 155 - 158 (1988)
Update date:2022-08-10
Topics:
Sakakura, Toshiyasu
Sasaki, Koushi
Tokunaga, Yuko
Wada, Keisuke
Tanaka, Masato
RhCl(CO)(Pr3)2-catalyzed and photoassisted carbonylation of decane leading to the formation of C11 aldehydes and/or 1-nonene was remarkably affected by the wavelength; irradiation with λ > 295 nm was essential to the formation of 1-nonene and undecanal.By cutting off λ < 325 nm, 1-nonene formation was completely suppressed, and a series of isomeric C11 aldehydes were obtained.
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