Journal of Organic Chemistry p. 5108 - 5110 (1991)
Update date:2022-08-11
Topics:
Wiberg, Kenneth B.
Hao, Shide
The enthalpies of hydration of a series of acyclic alkenes that lead to tert-alcohols were determined.Several pairs of alkenes that give the same alcohol were studied and gave the differences in enthalpy of formation of the alkenes.A consistent difference in Δ Hf of 1.84 kcal/mol was found between di- and trisubstituted alkenes.It was related to the difference in Δ Hf for pairs of exocyclic and endocyclic alkenes.The enthalpies of formation of the alcohols were obtained and were related to data for primary and secondary alcohols.
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