HYDROSTANNATION DU BICYCLOHEXENE-2: SYNTHESE ET IDENTIFICATION DES METHYL-4 ET METHYL-5 TRIMETHYLSTANNYL-3 CYCLOPENTENES DIASTEREOISOMERES

Article abstract of DOI:10.1016/0022-328X(83)80056-4

4-Methyl- and 5-methyl-3-trimethylstannylcyclopentenes were obtained from bicyclo<3.1.0>hex-2-ene through hydrostannation.The four isomers were identified by chemical and physicochemical methods such as 90 MHz 1H FT NMR spectroscopy which gives some conformational information in the series of 5-methyl-3-trimethylstannylcyclopentenes.