New Method for the Facile Reduction of α-Nitro Sulfones to Nitroalkanes via an Electron-Transfer-Hydrogen Atom Abstraction Mechanism

DOI: 10.1021/jo00252a001

Source and publish data:

Journal of Organic Chemistry p. 3897 - 3900 (1988)

Update date:2022-08-30

Topics:

Authors:

Chen, Jian

Tanner, Dennis D.

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Article abstract of DOI:10.1021/jo00252a001

The mechanism for the reduction of several α-nitro sulfones with 1,3-dimethyl-2-phenylbenzimidazoline (DMBI) was investigated.The reduction proceeds by a free-radical chain process where the initiation step and one of the propagation steps involve single electron transfer reactions.The synthetic utility of the reduction was investigated.

Full text of DOI:10.1021/jo00252a001

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