Journal of Organic Chemistry p. 3897 - 3900 (1988)
Update date:2022-08-30
Topics:
Chen, Jian
Tanner, Dennis D.
The mechanism for the reduction of several α-nitro sulfones with 1,3-dimethyl-2-phenylbenzimidazoline (DMBI) was investigated.The reduction proceeds by a free-radical chain process where the initiation step and one of the propagation steps involve single electron transfer reactions.The synthetic utility of the reduction was investigated.
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(1988)