Tetrahedron p. 5531 - 5538 (1989)
Update date:2022-08-30
Topics:
Gash, Rosslyn C.
MacCorquuodale, Finlay
Walton, John C.
The e.s.r. spectra derived from 7-bromo-5,6-epoxyheptene derivatives such as epoxygeranyl bromide (7) showed that the main free radical intermediates were tetrahydrofuranylmethyl radicals (11), formed by ring opening of the epoxide and subsequent exocyclisation of the unsaturated alkoxy radicals.The 7-oxabicyclo<2.2.1>heptanyl methyl radicals (12) were also formed via a double cyclisation.Products derived from both these intermediates were isolated from the reaction of (7) with tri-n-butyltin hydride.
View More
Suzhou Time-chem Technologies Co., Ltd.
Contact:0512-63983931/68086856
Address:No. 1326 of Binhe Road, New District, Suzhou, Jiangsu, P. R. China
Ningbo Inno Pharmchem Co., Ltd.
Contact:86-574-87319282
Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Shanghai Pengkai Chemical Co.,Ltd
Contact:+86-21-60526671
Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Shanghai Kefu Chemical Co.,Ltd.
Contact:+86-21-34616196
Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Contact:86-28-61993785
Address:No.70-13-21, North Section, Erhuan
Doi:10.1021/acs.joc.0c02643
(2021)Doi:10.1039/c5ra05077d
(2015)Doi:10.1021/acs.orglett.8b01534
(2018)Doi:10.1021/jo01072a621
(1960)Doi:10.1055/s-1987-27892
(1987)Doi:10.1039/c4ra07122k
(2014)
