Bulletin of the Chemical Society of Japan p. 3039 - 3040 (1987)
Update date:2022-08-16
Topics:
Tanoue, Yasuhiro
Terada, Akira
Not only rearrangement but also cyclization occurred in a Fries rearrangement of 1-methoxy-4-(4-methyl-2- and -3-pentenoyloxy)benzenes and gave 5,8-dihydroxy-4,4-dimethyl-3,4-dihydro-1(2H)-naphtalenone.The reduction and oxidation of the dihydronaphtalenone gave 5-hydroxy-8,8-dimethyl-5,6,7,8-tetrahydro-1,4-naphtalenedione and 8,8-dimethyl-7,8-dihydro-1,4,5(6H)-naphtalenetrione, respectively.
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