Catalytic asymmetric conjugate addition of Grignard reagents mediated by copper(I)-chiral bidentate phosphine complex

DOI: 10.1016/0040-4039(95)00759-6

Source and publish data:

Tetrahedron Letters p. 4275 - 4278 (1995)

Update date:2022-08-11

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Authors:

Kanai, Motomu

Tomioka, Kiyoshi

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Article abstract of DOI:10.1016/0040-4039(95)00759-6

A catalytic amount of a chiral phosphine I-copper iodide complex catalyzes the conjugate addition of organomagnesium chlorides to cycloalkenones and pentenolide to give the corresponding addition products in 94-72% ee.

Full text of DOI:10.1016/0040-4039(95)00759-6

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