Tetrahedron Letters p. 3663 - 3666 (1987)
Update date:2022-08-15
Topics:
Smith, Amos B.
Yokoyama, Yasushi
Dunlap, Norma K.
The total synthesis of dechloromikrolin (2Z), a minor fungal metabolite derived from Gilmaniella humicola Barron, has been achieved.The synthesis resulted in a reassigment of the stereochemistry of the C(2,3)-disubstituted olefinic bond from E to Z.The biosynthetic implications of this reassignment are discussed.
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