Catalytic Isomerisation of But-1-ene to 2-Methylpropene over Solid Acids: Comparison between DAF-1 and other Shape-selective Magnesium-containing Aluminophosphates and Aluminosilicates

DOI: 10.1039/C39930001861

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1861 - 1863 (1993)

Update date:2022-08-11

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Authors:

Natarayan, Srinivasan

Wright, Paul A.

Thomas, John Meurig

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Article abstract of DOI:10.1039/C39930001861

Although DAF-1 is a superior isomerisation catalyst at lower temperatures -1> both its activity and its selectivity, as well as its longevity, are inferior to those of H⁺-ferrierite and H⁺-Theta-1- in the range 350-400 deg C: the performance of MALPO-5, -11 and of -36 (M = Mg) is much poorer than that of DAF-1.

Full text of DOI:10.1039/C39930001861

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