Russian Chemical Bulletin p. 840 - 843 (1995)
Update date:2022-08-11
Topics:
Ryabova, R. S.
Osipova, G. F.
Travin, S. O.
The reactions occurring in an equilibrium mixture of 3-methyl-1-buten-3-ol and 3-methyl-2-buten-1-ol in 24-49 percent aqueous solutions of H2SO4 yield isoprene, 3-methyl-3-buten-1-ol, isobutylene, formaldehyde, 3-methylbutane-1,3-diol.Isobutylene is rapidly hydrated to give 2-methylpropan-2-ol.The presence of formaldehyde in the reaction mixture indicates that the transformations involve the reverse Prins reaction.On the basis of experimental and literature data, two most probable reactions were suggested.
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