Modification of Photochemical Reactivity by Zeolites: Selective Photorearrangement of α-Alkyldeoxybenzoins to p-Alkylbenzophenones in the Cavities of Faujasites

DOI: 10.1021/jo00257a043

Source and publish data:

Journal of Organic Chemistry p. 5384 - 5386 (1988)

Update date:2022-08-17

Topics:

Authors:

Corbin, D. R.

Eaton, D. F.

Ramamurthy, V.

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Article abstract of DOI:10.1021/jo00257a043

Photolysis of α-alkyldeoxybenzoins included in Li-X and Li-Y zeolites gave the corresponding rearranged p-alkylbenzophenones in near quantitative yields via the Norrish type I α-cleavage process.Such a striking behavior contrasts their normal reactivity in solution.

Full text of DOI:10.1021/jo00257a043

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