Tetrahedron p. 3819 - 3838 (1989)
Update date:2022-08-04
Topics:
Page, Philip C. Bulman
Harkin, Shaun A
Marchington, Allan P.
Niel, Monique B. van
Aminoketene dithioacetals add to α,β-unsaturated ketones to give 1,5-diketones after hydrolytic work-up.Upon treatment with acid or base, these diketones suffer intramolecular aldol reactions yielding cyclohex-2-en-1,4-dione monodithioacetals, interesting and useful synthetic equivalents of cyclohex-2-en-1,4-diones which readily undego conjugate addition and cycloaddition reactions.
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