Asymmetric Acetalization: A Simple Method for the Synthesis of Chiral α-Monosubstituted Cyclopentanones

DOI: 10.1021/jo00074a002

Source and publish data:

Journal of Organic Chemistry p. 5870 - 5872 (1993)

Update date:2022-08-03

Topics:

Authors:

Nishida, Mayumi

Nakaoka, Kazuyo

Ono, Shizuka

Yonemitsu, Osamu

Nishida, Atsushi

et al. et al.

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Article abstract of DOI:10.1021/jo00074a002

Acetalization of α-monosubstituted cyclopentanones with chiral hydroxy thiols under equilibrating conditions afforded a mixture of acetals in a highly diastereoselective manner, and deacetalization of the product affords optically active α-monosubstituted cyclopentanones.

Full text of DOI:10.1021/jo00074a002

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