Asymmetric Acetalization: A Simple Method for the Synthesis of Chiral α-Monosubstituted Cyclopentanones

DOI: 10.1021/jo00074a002

Source and publish data:

Journal of Organic Chemistry p. 5870 - 5872 (1993)

Update date:2022-08-03

Topics:

Authors:

Nishida, Mayumi

Nakaoka, Kazuyo

Ono, Shizuka

Yonemitsu, Osamu

Nishida, Atsushi

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00074a002

Acetalization of α-monosubstituted cyclopentanones with chiral hydroxy thiols under equilibrating conditions afforded a mixture of acetals in a highly diastereoselective manner, and deacetalization of the product affords optically active α-monosubstituted cyclopentanones.

Full text of DOI:10.1021/jo00074a002

Products guided by the article

Product name:Cyclopentanone, 2-undecyl-, (R)-

Cas No:116262-03-4

R&D Labs maybe for 116262-03-4

Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd

Contact:+86-533-5415882

Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Jiangsu Hualun Chemical Industry Co., Ltd

website:http://www.hualunchem.com

Contact:+86-0514-86464168 86507985

Address:39# Middle Renmin Road, Dinghuo Town
Jiangxi Hito Chemical Co., Ltd.

Contact:+86-792-3170318

Address:No. 6, Tianhong Ave., Xinghuo Industry Park, Yongxiu, Jiujiang, Jiangxi, China
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Wuhan Pengo Technology.,Ltd.

Contact:+86-27-67841589

Address:Add: 999 Gaoxin Road, Donghu New Technology Development Zone, Wuhan City, Hubei, China

Relevant to this article

Synthesis, characterization and no synthase inhibition testing of 2-aryl-5-aroyl-3,4,5,6-tetrahydropyrimidinium chlorides

Doi:10.1002/jhet.1925
(2015)
Addition Reactions of F-Alkyl Iodides to Carbon-Carbon Double Bonds Promoted by Metallic Tin(0)-Metal Salt System

Doi:10.1016/S0022-1139(00)82786-4
(1988)
Influence of the ester group during the enantioselective methylation of α-aldehyde esters via their chiral oxazolidine derivatives

Doi:10.1016/S0040-4039(00)96806-0
(1987)
(2R-trans)-2-Butyl-5-heptylpyrrolidine as a potent sigma receptor ligand produced by Streptomyces longispororuber

Doi:10.7164/antibiotics.53.467
(2000)
Kinetic investigation on the reactions of p-toluenesulfonyl chloride with p-substituted benzoic acid(s) in the presence of triethylamine in aprotic solvents

Doi:10.1002/kin.20400
(2009)
Angiotensin-converting enzyme inhibitors: Synthesis and biological activity of N-substituted tripeptide inhibitors

Doi:10.1248/cpb.38.110
(1990)

Article Doi