Tetrahedron Letters p. 6947 - 6948 (1991)
Update date:2022-08-16
Topics:
Moody, Christopher J.
Sie, Eric-Robert H. B.
Kulagowski, Janusz J.
Treatment of the phosphonates 3, derived from the diazophosphonates 1 and 2 by rhodium carbenoid O-H insertion reactions, with sodium hydride in THF results in intramolecular Wadsworth-Emmons reaction and formation of the cyclic ethers 4. Key words: Diazophosphonate; rhodium carbenoid; Wadsworth-Emmons; cyclic ether
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