Journal of Fluorine Chemistry p. 119 - 128 (1988)
Update date:2022-08-11
Topics:
Elsheimer, Seth
Dolbier, William R.
It was demonstrated through a kinetic study of the thermal rearrangement of cis,cis-1-fluoro-2-methyl-3-vinylcyclopropane to cis-3-fluoro-1,4-hexadiene that a single fluorine substituent lowers that activation barrier for rearrangement by about 2 kcal/mole as compared to 6.4 kcal/mole for geminal difluoro substitution.
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