Dissociation of Platinum(II) Nucleobase Complexes - Evidence for a Three-path Mechanism via a Five-coordinate Intermediate

DOI: 10.1039/c39950001759

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1759 - 1760 (1995)

Update date:2022-08-17

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Authors:

Mikola, Marjaana

Vihanto, Jouko

Arpalahti, Jorma

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Article abstract of DOI:10.1039/c39950001759

In thiourea assisted dissociation of 2+ (Guo = guanosine, dien = diethylenetriamine) in aqueous solution (pH = ca. 3) the nucleophile dependent reaction follows a three-path mechanism, in which the initial binding of the nucleophile to the complex and the ring-opening step of the terdentate dien ligand are reversible.

Full text of DOI:10.1039/c39950001759

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