Tetrahedron Letters p. 7011 - 7014 (1997)
Update date:2022-08-10
Topics:
Katritzky, Alan R.
Xie, Linghong
Zhang, Guifen
Griffith, Michael
Watson, Karen
Kiely, John S.
Resin-immobilized aldimines 5, derived from the condensation of amine-functionalized Rink polystyrene resin with aldehydes, react with Grignard reagents, lithium reagents or LiBH4 to afford a wide variety of primary amines in good to excellent yields upon trifluoroacetic acid cleavage. In this amine synthesis, Rink resin functions both as a solid support and as a NH protecting group.
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