Tetrahedron Letters p. 6221 - 6224 (1994)
Update date:2022-08-24
Topics:
Rai, Roopa
Collum, David B.
Reductions and free radical cyclizations of alkyl- and aryl bromides are effected in aqueous base by NaBH4 in conjunction with a base-soluble dialkyltin(IV) reagent and 4,4'-azobis(4-cyanovaleric acid) (ACVA). The aryl bromides reduce at lower rates under tin-free conditions using simply NaBH4-ACVA.
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