Ligand-Enabled, Copper-Catalyzed Regio- and Stereoselective Synthesis of Trialkylsubstituted Alkenylboronates from Unactivated Internal Alkynes

DOI: 10.1021/jacs.6b04646

Source and publish data:

Journal of the American Chemical Society p. 7528 - 7531 (2016)

Update date:2022-08-29

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Authors:

Itoh, Taisuke

Shimizu, Yohei

Kanai, Motomu

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Article abstract of DOI:10.1021/jacs.6b04646

We report the first copper-catalyzed regio- and stereoselective borylalkylation of dialkylsubstituted internal alkynes with bis(pinacolato)diboron and alkyl halides. A catalytically generated borylcopper species containing a novel π-accepting N-heterocycl

Full text of DOI:10.1021/jacs.6b04646

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