On pentaorganylstiborane. III. Regio- and diastereoselective additions of acetylenic and allenic organoantimony compounds to aldehydes

DOI: 10.1016/0022-328X(94)88110-3

Source and publish data:

Journal of Organometallic Chemistry p. 77 - 86 (1994)

Update date:2022-08-29

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Authors:

Zhang, Li-Jun

Mo, Xue-Sheng

Huang, Yao-Zeng

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Article abstract of DOI:10.1016/0022-328X(94)88110-3

The reaction of propargyl bromide (4a) with tributylstibine gave allenyltributylstibonium bromide (5), and its corresponding pentaorganylstiborane reacted with aldehyde to give homopropargylic alcohol (10a) exclusively in good yield.However, the reaction

Full text of DOI:10.1016/0022-328X(94)88110-3

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