Tributyltin hydride-induced free radical deoxygenation of the cyclic thionocarbonates of threo-2,3-dihydroxy esters and ketones

Article abstract of DOI:10.1080/00397919708005912

A practical and enantiospecific method for the synthesis of optically pure β-hydroxy esters and ketones is described. The key reaction is free radical deoxygenation of the cyclic thionocarbonates of threo-2,3-dihydroxy esters and ketones with tributyltin

Full text of DOI:10.1080/00397919708005912

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Synthetic Communications: An
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Organic Chemistry
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Tributyltin Hydride-Induced
Free Radical Deoxygenation of
the Cyclic Thionocarbonates
of Threo-2,3-Dihydroxy Esters
and Ketones
a
Ho-Sik Rho
a
Pharmaceutical & Health Science Research
Institute, Pacific Corporation , Yongin-Si Kyounggi-
do, 449-900, Korea
Published online: 22 Aug 2006.
To cite this article: Ho-Sik Rho (1997) Tributyltin Hydride-Induced Free Radical
Deoxygenation of the Cyclic Thionocarbonates of Threo-2,3-Dihydroxy Esters
and Ketones, Synthetic Communications: An International Journal for Rapid
Communication of Synthetic Organic Chemistry, 27:22, 3887-3893
To link to this article: http://dx.doi.org/10.1080/00397919708005912
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