Regio- and stereoselectivity in reactions of 2,3-cis- and trans-3-alkyl-2-vinylaziridines with organocopper reagents: Importance of 2,3-cis-stereochemistry in controlling selectivity

DOI: 10.1016/S0040-4039(97)01726-7

Source and publish data:

Tetrahedron Letters p. 7383 - 7386 (1997)

Update date:2022-08-11

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Authors:

Aoyama, Hiroshi

Mimura, Norio

Ohno, Hiroaki

Ishii, Kiyonori

Toda, Ayako

Tamamura, Hirokazu

Otaka, Akira

Fujii, Nobutaka

Ibuka, Toshiro

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Article abstract of DOI:10.1016/S0040-4039(97)01726-7

By treatment with organocopper reagents, N-activated 2,3-cis-3-alkyl-2-vinylaziridines produced exclusively (E)-allyl amines in high yields, presumably via an anti-S(N)2' reaction pathway. On the other hand, under otherwise identical conditions, N-activat

Full text of DOI:10.1016/S0040-4039(97)01726-7

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