Acetyl bromide-alcohols as convenient reaction systems for: a) Removal of N-tert-Boc, N-Cbz and N-Ac protective groups, b) Esterifications and transesterifications, c) Debenzylation of aryl-O-benzyl ethers

Article abstract of DOI:10.1080/00397919908086117

Hydrogen bromide generated in situ by the addition of acetyl bromide to alcohols is a useful reagent for esterifications and transesterifications; N- tert-Boc, N-Cbz, and N-Ac deprotections; and debenzylation reactions.

Full text of DOI:10.1080/00397919908086117

This article was downloaded by: [University of California, San Francisco]
On: 20 August 2014, At: 02:11
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Acetyl Bromide-Alcohols as
Convenient Reaction Systems
for: a) Removal of N-tert-Boc,
N-Cbz And N-Ac Protective
Groups, b) Esterifications
and Transesterifications, c)
Debenzylation of Aryl-O-Benzyl
Ethers
Anat Lesk And a & Abraham Nudelman a
a Department of Chemistry , Bar Ilan University ,
Ramat Gan, 52900, Israel
Published online: 17 Sep 2007.
To cite this article: Anat Lesk And & Abraham Nudelman (1999) Acetyl Bromide-
Alcohols as Convenient Reaction Systems for: a) Removal of N-tert-Boc, N-Cbz And
N-Ac Protective Groups, b) Esterifications and Transesterifications, c) Debenzylation
of Aryl-O-Benzyl Ethers, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 29:8, 1405-1408, DOI:
10.1080/00397919908086117
To link to this article: http://dx.doi.org/10.1080/00397919908086117
PLEASE SCROLL DOWN FOR ARTICLE

Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions