The reaction of benzene with diethylamine in the presence of an iridium(I)/mercury(II) based system: a model route for the direct amination of aromatic hydrocarbons

DOI: 10.1016/0022-328X(94)05391-N

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C3 (1995)

Update date:2022-08-10

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Authors:

Diversi, Pietro

Ermini, Luca

Ingrosso, Giovanni

Lucherini, Antonio

Pinzino, Calogero

Sagramora, Laura

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Article abstract of DOI:10.1016/0022-328X(94)05391-N

N,N-Diethylaniline is formed under mild conditions either by the direct amination of benzene with diethylamine in the presence of 5-C5Me5)(CO)2> 1 and HgSO4, or by reacting (C6H5)2Hg or C6H5HgCl/Ag2SO4 with diethylamine in the presence of 1.A preliminary investigation about the chemistry underlying these reactions is also reported.Keywords: Iridium; Amination; C-H activation; N-H activation; Mercury; Catalysis

Full text of DOI:10.1016/0022-328X(94)05391-N

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