Alkane carbonylation photocatalyzed by aromatic ketones under high CO pressure

DOI: 10.1016/0040-4039(92)88155-X

Source and publish data:

Tetrahedron Letters p. 2119 - 2122 (1992)

Update date:2022-08-31

Topics:

Authors:

Boese, William T.

Goldman, Alan S.

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Article abstract of DOI:10.1016/0040-4039(92)88155-X

Aromatic ketones photocatalyze the carbonylation of alkanes to the corresponding aldehydes at room temperature under high CO pressures (20 - 80 atm). In the presence of CCl₄, cyclohexanecarbonylchloride is formed from cyclohexane; this reaction was used to determine the rate of addition of cyclohexyl radical to CO.

Full text of DOI:10.1016/0040-4039(92)88155-X

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