Tetrahedron Letters p. 2119 - 2122 (1992)
Update date:2022-08-31
Topics:
Boese, William T.
Goldman, Alan S.
Aromatic ketones photocatalyze the carbonylation of alkanes to the corresponding aldehydes at room temperature under high CO pressures (20 - 80 atm). In the presence of CCl4, cyclohexanecarbonylchloride is formed from cyclohexane; this reaction was used to determine the rate of addition of cyclohexyl radical to CO.
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Doi:10.1021/acs.orglett.7b03331
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(1997)Doi:10.1002/ejoc.201800622
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(2001)
