Formation of N,N'-Disubstituted Methanediamine Derivatives from Hexamethyldisilazane and Aldehydes via Stepwise Reactions

DOI: 10.1246/bcsj.61.609

Source and publish data:

Bulletin of the Chemical Society of Japan p. 609 - 611 (1988)

Update date:2022-08-18

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Authors:

Nishiyama, Kozaburo

Saito, Masaki

Oba, Makoto

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Article abstract of DOI:10.1246/bcsj.61.609

The ZnCl2-catalyzed reaction of aldehydes with hexamethyldisilazane (HMDS) resulted in the formation of N,N'-disubstituted methanediamines, which were found to be formed stepwisely via 1:1- and 1:2-adducts of HMDS and aldehydes.

Full text of DOI:10.1246/bcsj.61.609

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