Tetrahedron Letters p. 205 - 208 (1988)
Update date:2022-08-23
Topics:
Leduc, P.
Battioni, P.
Bartoli, J. F.
Mansuy, D.
A biomimetic electrochemical system using manganese tetraphenylporphyrin chloride and imidazole as catalysts and acetic acid as a proton donor, activates dioxygen and epoxidizes various alkenes with good yields based on consumed pairs of electrones (around 50percent) and rates (around 1 turnover per min), and oxidizes alkanes into alcohols and ketones.
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