Improved synthesis of [Mn(CO)5OCIO3], a versatile reagent for the preparation of cationic (Polyene)manganese(I) complexes. Crystal structure of [(η4-1,5-cyclooctadiene)Mn(CO)4] CIO4

DOI: 10.1021/om9805739

Source and publish data:

Organometallics p. 5586 - 5590 (1998)

Update date:2022-08-11

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Authors:

Chaffee, Stuart C.

Sutton, Joshua C.

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Article abstract of DOI:10.1021/om9805739

The title complex is synthesized in one step from [Mn₂(CO)₁₀] and is used to prepare cationic [(η⁴-diene)Mn(CO)₄]⁺ and [(η⁶-triene)Mn(CO)₃]⁺ complexes, including [(η⁴-1,5-cyclooctadiene)Mn(CO)₄]CIO₄, for which an X-ray crystal structure is reported. The kinetics of [(η⁴-norbornadiene)Mn(CO)₄]CIO₄ conversion to cis-[(CH₃CN)₂Mn(CO)₄]⁺ are also studied.

Full text of DOI:10.1021/om9805739

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