Stereoselective synthesis and some reactions of β-(η6-arene)Cr(CO)3 complexes of podocarpic acid derivatives

DOI: 10.1016/S0022-328X(97)00220-9

Source and publish data:

Journal of Organometallic Chemistry p. 225 - 247 (1997)

Update date:2022-08-10

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Authors:

Clark, George R.

Kuipers, Bianca

Metzler, Michael R.

Nguyen, Manh H.

Woodgate, Paul D.

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Article abstract of DOI:10.1016/S0022-328X(97)00220-9

The stereoselective synthesis of a number of (η⁶-arene)tricarbonylchrorniurn(0) complexes derived from podocarpic acid has been achieved in good to excellent yield. The stereochemistry of complexes 36 and 37 was established by X-ray crystallography. Reactions of some of the deprotonated complexes with electrophiles were investigated.

Full text of DOI:10.1016/S0022-328X(97)00220-9

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