Tetrahedron Letters p. 4281 - 4284 (1988)
Update date:2022-08-16
Topics:
Schaumann, Ernst
Kirsching, Andreas
Lithiated allylsilanes 1 undergo smooth addition to epoxides 4 with variable α,γ regioselectivity yielding the C-silylated enols 5,7 and 6,8, respectively. γ-Selectivity can be successfully enhanced by use of cuprates.
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(1962)Doi:10.1016/S0040-4020(01)98979-3
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(1985)
