ON THE OXYBROMIDE CHEMISTRY RATE CONSTANS WITH CERIUM IONS IN THE FIELD-KOEROES-NOYES MECHANISM OF THE BELOUSOV-ZHABOTINSKII REACTION: THE EQUILIBRIUM HBrO2 + BrO(1-) + H(1+) 2BrO2. + H2O

Article abstract of DOI:10.1021/j100412a101

A revised set of rate constants at 20 deg C and in M H2SO4 is developed for the Field-Koeroes-Noyes mechanism of the 4Ce(III) + BrO3(1-) + 5H(1+) <*> 4Ce(IV) + HOBr + 2H2O component of the oscillatory Belousov-Zhabotinskii reaction.The mechanism involves