INFRARED MATRIX ISOLATION EVIDENCE FOR THE FORMATION OF (η5-CYCLOPENTADIENYL)TRICARBONYL-MOLYBDENUM AND -TUNGSTEN RADICALS IN CARBON MONOXIDE MATRICES AT 12 K

DOI: 10.1016/0022-328X(83)80205-8

Source and publish data:

Journal of Organometallic Chemistry p. C37 - C41 (1983)

Update date:2022-08-17

Topics:

Authors:

Mahmoud, Khalil A.

Rest, Antony J.

Alt, Helmut G.

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Article abstract of DOI:10.1016/0022-328X(83)80205-8

Infrared spectroscopic evidence including 13CO labelling and energy-factored force-field fitting is presented for the first time to show that the radicals (η⁵-C5H5)M(CO)3 radical (M=Mo, W) and HCO are produced on photolysis of (η⁵-C5

Full text of DOI:10.1016/0022-328X(83)80205-8

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