STEREOSELECTIVE SYNTHESIS OF METHYL (1R) TRANS- AND (1R) CIS-HEMICARONALDEHYDES FROM NATURAL TARTARIC ACID: APPLICATION TO THE SYNTHESIS OF S-BIOALLETHRIN AND DELTAMETHRIN INSECTICIDES.

DOI: 10.1016/S0040-4020(01)80130-7

Source and publish data:

Tetrahedron p. 3039 - 3052 (1989)

Update date:2022-08-28

Topics:

Authors:

Krief, A.

Dumont, W.

Pasau, P.

Lecomte, Ph.

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Article abstract of DOI:10.1016/S0040-4020(01)80130-7

Very efficient enantioselective syntheses of (1R)-trans-and cis-hemicaronaldehydes precursors of (1R)-trans chrysanthemic acid and its (1R)-cis dibromovinyl analogue starting from natural tartaric acid or D-mannitol are described.They are based on the rea

Full text of DOI:10.1016/S0040-4020(01)80130-7

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