Tetrahedron Letters p. 2763 - 2766 (1997)
Update date:2022-08-11
Topics:
Barluenga, Jose
Sanz, Roberto
Fananas, Francisco J.
N-Allyl-N-(2-lithioallyl)amines undergo intramolecular carbametallation via 5-exo or 6-endo addition. The course of the reaction depends on the nitrogen electron density. 3-Functionalized-4-methylenepyrrolidines can be synthesized.
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