2018
Tianyong Zhang et al. / Chinese Journal of Catalysis 36 (2015) 2011–2019
Graphical Abstract
Chin. J. Catal., 2015, 36: 2011–2019 doi: 10.1016/S1872‐2067(15)60920‐2
Synthesis, characterization and catalytic reactivity of pentacoordinate iron
dicarbonyl as a model of the [Fe]‐hydrogenase active site
Tianyong Zhang, Liao Sheng, Qiusheng Yang, Shuang Jiang, Yanhong Wang,
Chaohui Jin, Bin Li*
Tianjin University; Hebei University of Technology
Fe(CO)2PCy3(NN), (NN = phenylenediamine dianion ligand, N2H2Ph2–) exhibited
interesting reversible protonation/deprotonation activity of the diimine ligand
similar to the active site of Hmd. The catalytic transfer hydrogenation of benzo‐
quinone to hydroquinone was catalyzed under mild conditions by this model
complex with 89% conversion and 40% yield.
[15] Noyori R, Koizumi M, Ishii D, Ohkuma T. Pure Appl Chem, 2001, 73:
Nomenclature
227
[16] Peris E, Lee J C Jr, Rambo J R, Eisenstein O, Crabtree R H. J Am
Chem Soc, 1995, 117: 3485
[17] Matsumoto T, Chang H C, Wakizaka M, Ueno S, Kobayashi A,
Nakayama A, Taketsugu T, Kato M. J Am Chem Soc, 2013, 135:
8646
[18] Li B, Liu T B, Popescu C V, Bilko A, Darensbourg M Y. Inorg Chem,
2009, 48: 11283
[19] Liu T B, Li B, Popescu C V, Bilko A, Perez L M, Hall M B,
Darensbourg M Y. Chem Eur J, 2010, 16: 3083
[20] Liaw W F, Lee N H, Chen C H, Lee C M, Lee G H, Peng S M. J Am
Chem Soc, 2000, 122: 488
[21] Shima S, Lyon E J, Sordel‐Klippert M, Kauss M, Kahnt J, Thauer R K,
Steinbach K, Xie X L, Verdier L, Griesinger C. Angew Chem. Int. Ed.
2004, 43: 2541
[22] Mejia‐Rodriguez R, Chong D, Reibenspies J H, Soriaga M P,
Darensbourg M Y. J Am Chem Soc, 2004, 126: 12004
[23] Liu T B, Wang M, Shi Z, Cui H G, Dong W B, Chen J, Akermark B,
Sun L C. Chem Eur J, 2004, 10: 4474
[24] Kaur‐Ghumaan S, Schwartz L, Lomoth R, Stein M, Ott S. Angew
Chem Int Ed, 2010, 49: 8033
Epa—Anodic peak potential, V
Epc—Cathodic peak potential, V
Ea—Activation energy, kJ/mol
References
[1] Shima S, Thauer R K. Chem Rec, 2007, 7: 37
[2] Thauer R K, Klein A R, Hartmann G C. Chem Rev, 1996, 96: 3031
[3] Fontecilla‐Camps J C, Volbeda A, Cavazza C, Nicolet Y. Chem Rev,
2007, 107: 4273
[4] Dey S, Das P K, Dey A. Coordin Chem Rev, 2013, 257: 42
[5] Guo Y S, Wang H X, Xiao Y M, Vogt S, Thauer R K, Shima S, Volkers
P I, Rauchfuss T B, Pelmenschikov V, Case D A, Alp E E, Sturhahn
W, Yoda Y, Cramer S P. Inorg Chem, 2008, 47: 3969
[6] Hiromoto T, Ataka K, Pilak O, Vogt S, Stagni M S, Meyer‐Klaucke W,
Warkentin E, Thauer R K, Shima S, Ermler U FEBS Lett, 2009, 583:
585
[7] Salomone‐Stagni M, Stellato F, Whaley C M, Vogt S, Morante S,
Shima S, Rauchfuss T B, Meyer‐Klaucke W. Dalton Trans, 2010, 39:
3057
[25] Turrell P J, Hill A D, Ibrahim S K, Wright J A, Pickett C J. Dalton
Trans, 2013, 42: 8140
[26] Song L C, Hu F Q, Wang M M, Xie Z J, Xu K K, Song H B. Dalton
Trans, 2014, 43: 8062
[8] Chen D F, Scopelliti R, Hu X L. J Am Chem Soc, 2010, 132: 928
[9] Shima S, Pilak O, Vogt S, Schick M, Stagni M S, Meyer‐Klaucke W,
Warkentin E, Thauer R K, Ermler U. Science, 2008, 321: 572
[10] Shima S, Schick M, Kahnt J, Ataka K, Steinbach K, Linne U. Dalton
Trans, 2012, 41: 767
[27] Zuo W W, Lough A J, Li Y F, Morris R H. Science, 2013, 342: 1080
[11] Schultz K M, Chen D F, Hu X L. Chem Asian J, 2013, 8: 1068
[12] Yang X Z, Hall M B. J Am Chem Soc, 2009, 131: 10901
[13] Crabtree R H, Siegbahn P E M, Eisenstein O, Rheingold A L, Koetzle
T F. Acc Chem Res, 1996, 29: 348
Page numbers refer to the contents in the print version, which include
both the English version and extended Chinese abstract of the paper. The
online version only has the English version. The pages with the extended
Chinese abstract are only available in the print version.
[14] Szymczak N K, Tyler D R. Coordin Chem Rev, 2008, 252: 212