Chemistry Letters p. 245 - 248 (1985)
Update date:2022-08-11
Topics:
Funakoshi, Masaki
Komiyama, Hiroshi
Inoue, Hakuai
Ni28Ti72 alloy catalyst was found to have a high selectivity for the hydogenation of acrolein to propionaldehyde.However, both the carbon-carbon double bond and the formyl group were hydogenated by supported nickel or nickel ultra-fine particles, leading to the simultaneous production of 1-propanol together with propionaldehyde.The retardation of the formyl group hydrogenation by alloying has been suggested to be caused by the electronic effect.
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