PHOTO-INDUCED OXIDATIVE ADDITION OF BUTYL IODIDE TO A DIMERIC RHODIUM(I) COMPLEX. AN ELECTRON TRANSFER CHAIN MECHANISM

DOI: 10.1246/cl.1982.719

Source and publish data:

Chemistry Letters p. 719 - 722 (1982)

Update date:2022-08-28

Topics:

Authors:

Fukuzumi, Shunichi

Nishizawa, Nobuaki

Tanaka, Toshio

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Article abstract of DOI:10.1246/cl.1982.719

Irradiation of an acetonitrile solution of ²⁺ (dicp = 1,3-diisocyanopropane) in the presence of butyl iodide by the visible light at 553 nm produces the adduct, ²⁺, in a high quantum yield, e.g., Φ=25.2.A photo-induced electron transfer chain mechanism is presented based on the effects of electron acceptors (p-dinitrobenzene, p-benzoquinone, and chloranil) and radical scavengers (oxygen and isopentyl nitrite) on the photochemical reaction.

Full text of DOI:10.1246/cl.1982.719

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